多齿含噁唑啉基配体金属银配位聚合物的合成及催化性质研究

Coordination polymers have receieved great attention in recent years due to their variable structures, interesting properties and potential applications. However, it is still difficult to predict and control the structure and property of the complexes. In this project, there are two main parts: Firstly,different kinds of 2-oxazoline-containing ligands and their functional coordination polymers will be designed and synthesized. The coordination polymers with various structures will be tuned and controlled by changing the reaction conditions, and complexes with chiral structure will be screened by the structural characterization. Moreover, such functional coordination polymers assembled and its structure regulation will be studied. Secondly, the synthesized coordination polymers are used to catalysize the reaction as catalysts, and the chiral coordination polymer applications in catalytic asymmetric synthesis of the propargylamine derivatives will be studied. Furthermore, that the reaction between imine and 1,3 - diene derivatives are affected by structure of coordination polymers will be explored and the efficient performance of the catalyst will be screened.

配位聚合物因其多样的结构、有趣的性能以及潜在的应用而受到人们的广泛关注。其中，配位聚合物结构和性能的调控以及结构和性能的关系等问题是该领域研究的热点和难点。本项目主要包括以下两个方面：一是，设计合成含噁唑啉基配体的功能配位聚合物。通过改变反应条件，得到一系列结构不同的配位聚合物并加以表征，筛选出手性配位聚合物。研究探讨该类功能配位聚合物组装合成的条件及其结构调控。二是，利用合成得到的配位聚合物作为催化剂研究其催化性能。研究手性配位聚合物在不对称催化醛、胺和炔三组份偶联反应中的应用，探讨配位聚合物的结构对1,3-二烯衍生物和亚胺化合物环化反应的影响，筛选得到高效性能的催化剂。

配位聚合物因其多样的结构、有趣的性能以及潜在的应用而受到人们的广泛关注。其中，配位聚合物结构和性能的调控以及结构和性能的关系等问题是该领域研究的热点和难点。本项目主要包括以下两个方面：一是，设计合成含噁唑啉基配体的功能配位聚合物。通过改变反应条件，得到一系列结构不同的配位聚合物并加以表征，筛选出手性配位聚合物。研究探讨该类功能配位聚合物组装合成的条件及其结构调控。二是，利用合成得到的配位聚合物作为催化剂研究其催化性能。研究配位聚合物配位聚合物结构催化重氮化合物和烯烃偶联反应的影响，获得高效性能催化剂。