焚烧销毁化学战剂中的化学动力学问题

There are nearly two million rounds of chemical weapons have been buried in our land by Japanese during the world war 2, including Mustard gas, Lewisite, Dibenzylchloroarsine and Dibenzylcyanarsine,which should be destroyed by 2007, as a rull of the Internation Treaty on forbidden of chemical warfare. In America,by using a serial incinerators several hundred tons of chemical warfare of Mustard gas and Lewisite have been destroyed successfully at Johenston island. The mission of our project is to sduty of the decomposition of Mustard gas and some of the related agents with concentrating on the bond broken mechanism,especially the chlorine-carbon bond in these materials,and to determine thire reaction rate constants. The mission of these project has been reached,which provided a scientific basis for the incineration destruction of related chemical warfare.

焚烧销毁化学战剂是即将在我国东北地区由日本人主持的重大工程。安全处置和科学控制是关系周边环境和可持续发展的大事。预先研究和掌握其中的高温下化学战剂裂解解毒机理和基本物理化学参数的测定是必要的。本项目采用近芥子气结构近无毒的物质在单脉冲激波管中实验研究达到这一目标，配合理论计算分析，预期为重要工程的科学控制提供依据。