反应-分离-传递网络递次联动机理与集成方法研究

To make a chemical production system optimal in a whole, it is necessary to identify the synergy and linkage mechanism among the reaction - separation system, energy and mass exchange networks and system utilities, perform the system-wide multi-level, multi-variable integration, identify and design the optimal system.. Based on the chemical reaction kinetics, the mass and energy transfer mechanism of separation, this project intends to build the quantitative reaction - separation system model by the strictly algebraic reasoning and image analysis, identify the linkage mechanism of reaction and separation from internal field synergy and external macro performance. With the key parameter of the reaction-separation system versus performance curve constructed, and coupled with the composite curve of the exchange network, the common coupling linkage disciplinarian between the reaction - separation system and exchange network can be analyzed. For the reaction - separation system and exchange network with synchronous and asynchronous variation, the relationship between the amount of overall performance and the key operating parameter will be discussed, and coupling process integration strategy will be proposed. An integrated total site analysis and optimization methodology will be established to provide the theoretical basis for industrial system integration and design optimization.

为了使化工生产系统整体最优，需确定反应-分离系统、及其与传递网络、公用工程系统的协同关系和联动机理，对全系统进行多层次、多变量集成，辨识和设计真正意义上的最优系统。. 本项目拟基于反应动力学机理和分离过程物质和能量的传递机理进行严格的代数推理和图像分析，建立反应-分离系统的整体模型，从内部场协同和外部整体宏观表现两个方面探索反应和分离的联动机理；确定反应-分离系统与传递网络耦合的关键参数，构建反应-分离系统的关键参数-性能关系曲线，将其与传递网络的复合关系曲线耦合，分析反应-分离系统和传递网络二者之间通用的定量的耦合联动规律；针对同步和异步的反应-分离系统与传递网络系统，探讨系统整体能效与反应分离系统关键操作参数的关系，提出反应-分离-传递网络的耦合集成策略；建立全过程的集成分析方法和优化理论，为过程工业系统集成和优化设计提供理论基础。

为使化工生产系统整体最优，需确定反应-分离系统、及其与传递网络的协同关系和联动机理，对全系统进行多层次、多变量集成，辨识和设计真正意义上的最优系统。. 项目基于反应动力学机理和分离过程物质和能量的传递机理，建立了反应-分离系统的整体模型，基于严格的代数推理和图像分析探讨了反应-分离系统的能效随关键参数的变化规律；考虑反应-分离系统与传递网络耦合的关键参数，构建反应-分离系统的关键参数-性能关系曲线，分别耦合能量和质量复合曲线与反应-分离系统，构建图像法探讨了反应-分离系统和传递网络的互动影响规律；基于多层次的集成优化研究了系统整体能效与反应分离系统关键操作参数的关系，提出反应-分离-传递网络的耦合集成策略；建立了全过程的集成分析方法和优化理论，为过程工业系统集成和优化设计提供理论基础。