Keggin-型多酸有机碱原位降解共价修饰研究

Organical functionalization of polyoxometalates (POMs) is a hot topic among current frontier of POMs chemistry. However, technical bottlenecks of harsh reaction conditions, complicated multi-step synthesis, and environmental unfriendly process, have been greatly restricted its development and application, though a variety of surface modification methods have been developed. To solve these problems, exploration of a new synthetic technique with green, economic, and efficient characteristics is an effective way. On the basis of previous works, we have innovatively developed a green water-phase synthesis technology, under which the Keggin-type POMs are degraded in situ and then organically functionalized. By this new strategy, some technical problems can be effectively solved. Comprehensive study of this project will enrich the synthetic method of POMs-organic modification chemistry, refine the reaction route, broaden research ideas, and promote its further development and application in various domains. Undoubtedly, the new synthetic technology will open new opportunities and broad prospects for POMs-organic modification chemistry.

多酸有机修饰化学是多酸化学的热点研究领域，尽管已发展出多种表面修饰手段，然而反应条件苛刻、合成步骤复杂、环境不友好等技术瓶颈极大的限制了该体系在各个领域的发展与应用。探索开发绿色、经济、高效的新型有机化合成反应是解决当前反应体系技术难题的有效途径。本项目在前期工作基础上，另辟蹊径，创新性地开发出一种绿色水相反应体系下Keggin-型多酸原位降解有机化合成技术，该策略能够有效地解决传统多酸有机化的诸多技术难题。本课题的深入研究将丰富多酸有机修饰化学的合成方法、完善反应路线、拓宽研究思路与方向，推动多酸有机衍生物在各个领域的发展与应用。可以肯定的是，新型合成技术的开发为多酸有机修饰化学带来了新的机遇和广阔的发展前景。

多酸有机修饰化学是多酸化学的热点研究领域，尽管已发展出多种表面修饰手段，然而反应条件苛刻、合成步骤复杂、环境不友好等技术瓶颈极大的限制了该体系在各个领域的发展与应用。探索开发绿色、经济、高效的新型有机化合成反应是解决当前反应体系技术难题的有效途径。本项目在前期工作基础上，另辟蹊径，创新性地开发出一种绿色水相反应体系下Keggin-型多酸原位降解有机化合成技术，该策略能够有效地解决传统多酸有机化的诸多技术难题。本课题的深入研究将丰富多酸有机修饰化学的合成方法、完善反应路线、拓宽研究思路与方向，推动多酸有机衍生物在各个领域的发展与应用。可以肯定的是，新型合成技术的开发为多酸有机修饰化学带来了新的机遇和广阔的发展前景。