钒---氧簇合物的设计合成，结构，功能及水热化学研究

The precusor of coordination cation acceptors as bridging groups will be synthesized by molecule design, and then linked V-O clusters/oxides donors containing mixed metal atoms to form one-, two- or three-dimensional structures by polymeric reaction between donors and acceptors under rational condition. The structures of V-O polymers, the magnetic properties of V-O clusters with low/mixed valence and the condition of controlling the demensional of polymers will be deeply studied.

采用水热技术，设计合成不同的配位单元作为桥配体，进而与钒-氧簇合物（氧化物）亚单樽埃诓煌跫拢玫揭唬蛉藁谢肿庸烫澹芯科浣峁共⑾低车刈芙岷铣晒媛伞Ｍ倍愿美嗷衔锏拇判约暗缪灾式醒芯俊８每翁庾魑肿涌蒲Ш凸烫蹇蒲У那帕海耘湮痪酆匣В藁烫寤Ъ拔藁肿踊Ь哂惺种匾囊庖濉