新手性催化剂催化下手性加成反应的研究
基本信息
结项摘要
本项申请提出了新的较高立体选择性的手性催化剂[(R)TTCA]n.M，在该催化剂催化下进行加成反应研究，合成了手性δ-酮腈，δ-酮酸甲酯，它们都是合成一些类天然产物或者手性有机物的中间体。这一研究为不对称合成提供了新的手性催化剂源。作为应用，提出了由α蒎烯出发合成紫杉醇前体AB环的新方法，以上研究内容国内外文献均未见报道，属原始创新性研究。
项目摘要
项目成果
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数据更新时间：2023-05-31
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李叶芝的其他基金
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